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Sagot :
Br- + 2MnO4- + 2H+ → BrO3- + 2MnO2 + H2O
Further explanation
Given
MnO4- + Br- = MnO2 + BrO3-
Required
The half-reaction
Solution
In acidic conditions :
1. Add the coefficient
2. Equalization O atoms (add H₂O) on the O-deficient side.
3. Equalization H atoms (add H⁺ ) on the H -deficient side. .
4. Equalization of charge (add electrons (e) )
5. Equalizing the number of electrons and then adding the two half -reactions together
Oxidation : Br- → BrO3-
Reduction : MnO4- → MnO2
- Equalization O atoms
Br- + 3H2O → BrO3-
MnO4- → MnO2 + 2H2O
- Equalization H atoms
Br- + 3H2O → BrO3- + 6H+
MnO4- + 4H+ → MnO2 + 2H2O
- Equalization of charge
Br- + 3H2O → BrO3- + 6H+ + 6e- x1
MnO4- + 4H+ + 3e- → MnO2 + 2H2O x2
- Equalizing the number of electrons and then adding the two half -reactions together
Br- + 3H2O → BrO3- + 6H+ + 6e-
2MnO4- + 8H+ + 6e- → 2MnO2 + 4H2O
Br- + 2MnO4- + 3H2O + 8H+ + 6e- → BrO3- + 2MnO2 + 6H+ + 4H2O + 6e-
Br- + 2MnO4- + 2H+ → BrO3- + 2MnO2 + H2O
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