Welcome to Westonci.ca, the place where your questions find answers from a community of knowledgeable experts. Explore a wealth of knowledge from professionals across various disciplines on our comprehensive Q&A platform. Discover in-depth answers to your questions from a wide network of professionals on our user-friendly Q&A platform.

In a titration of nitrous acid with NaOH, the pH of the solution is 3.14 when the moles of HNO2 and the moles of NO2-- are equal. What is the Ka of nitrous acid?

Sagot :

Answer:

[tex]Ka=3.98x10^{-4}[/tex]

Explanation:

Hello there!

In this case, since the modelling of titration problems can be approached via the Henderson-Hasselbach equation to set up a relationship between pH, pKa and the concentration of the acid and its conjugate base, we can write:

[tex]pH=pKa+log(\frac{[NO_2^-]}{[HNO_2]} )[/tex]

Whereas the pH is given as 3.14 and the concentrations are the same, that is why the pH would be equal to the pKa as the logarithm gets 0 (log(1)=0); thus, we can calculate the Ka via:

[tex]Ka=10^{-pKa}=10^{-3.14}\\\\Ka=3.98x10^{-4}[/tex]

Best regards!