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250 mL of 1.5 M nitric acid is mixed with 250 mL of 2.5 M sodium hydroxide. Calculate the pH of the resulting mixture.

Sagot :

Answer:

pH = 13.7.

Explanation:

Hello there!

In this case, as we set up the chemical reaction between nitric acid and sodium hydroxide:

[tex]NaOH+HNO_3\rightarrow NaNO_3+H_2O[/tex]

It is possible to realize there is a 1:1 mole ratio of acid to base, thus, we next compute the moles of each one:

[tex]n_{acid}=0.25L*1.5mol/L=0.375mol\\\\n_{base}=0.25L*2.5mol/L=0.625mol[/tex]

In such a way, since the base react with more moles, there is leftover that we compute as shown below:

[tex]n_{base}^{leftover}=0.25mol[/tex]

Afterwards, we compute the concentration given the new volume of 500 mL (0.500 L), as both volumes are added up:

[tex][base]=0.25mol/0.500L=0.5M[/tex]

Now, since sodium hydroxide is such a strong base, we compute the pOH first:

[tex][OH^-]=[base]=0.5M[/tex]

[tex]pOH=-log([OH^-])=-log(0.5M)\\\\pOH=0.30[/tex]

And the pH:

[tex]pH=14-0.30\\\\pH=13.7[/tex]

Best regards!