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Another method for creating a buffer, in situ, is to add an appropriate amount of a strong base, e.g., NaOH, to a weak acid OR add an appropriate amount of a strong acid, e.g., HNO3, to a weak base. As an example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate. The acetate is created by the reaction of acetic acid and the strong base, hydroxide. Given this information, which of the following, when mixed with the appropriate amount of HCl, would create a buffer solution?

a. HNO3
b. HClO2
c. LiCl
d. NH3


Sagot :

Answer:

As an example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate. The acetate is created by the reaction of acetic acid and the strong base, hydroxide.

When HClO2 is mixed with the appropriate amount of HCl it would create a buffer solution. That is option B.

Methods used to form buffer solution

A buffer solution is the solution that resists a change in pH of a solution when acid or base is added because it is made up of weak acid and the conjugate base or weak base and the conjugate acid.

The methods that can be used to form a buffer solution include:

  • Adding a strong base to a weak acid: For example, mixing 1.0 mol of acetic acid with 0.5 mol of NaOH will result in a buffer solution with 0.5 mol of acetic acid and 0.5 mol of acetate.

  • Adding a weak acid to a conjugate base: For example HCl is a strong acid which will react with a conjugate base such as HClO2.

Although HCl is a strong acid, it can be converted to a weak acid through dilution with water. It is in this context that it can be used to form a buffer solution.

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