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Polonium-208 is an alpha emitter with a half-life of 2.90 years. How many milligrams of polonium from an original sample of 2.00 mg will remain after 8.00 years

Sagot :

Answer:

0.296 mg

Explanation:

8.00/2.90 half lives have passed, so this means the remaining mass is

[tex]2.00 {(0.5)}^{8.00 \div 2.90} [/tex]

which is about 0.296 mg.

The amount of polonium remaining after 8.00 years is 0.296 mg. This is obtained by using rate law of first order kinetics.

What is the rate law of first order kinetics and the half-life of the compound?

The expression for the rate law for first order kinetics is

k = [tex]\frac{2.303}{t}log\frac{a}{a-x}[/tex] years⁻¹

Where,

k - rate constant

t - time passed by the sample

a - initial amount of the reactant

a-x  - final amount of the reactant

The expression for the half-life of the compound is

[tex]t_{\frac{1}{2}}=\frac{0.693}{k}[/tex] years

Calculating the amount of polonium remained after 8.00 years:

Given that,

A Polonium-208 is an alpha emitter with a half-life of 2.90 years.

I.e., [tex]t_{\frac{1}{2}}[/tex] = 2.90 years

Then,

2.90 = (0.693)/k

⇒ k = (0.693)/(2.90) = 0.2389 years⁻¹

Then,

for t = 8.00 years,

Since we have rate law of first order kinetics as

k =  [tex]\frac{2.303}{t}log\frac{a}{a-x}[/tex]

⇒ k = (2.303/8.00) log(a/a-x)

Where the initial amount of the reactants is a = 2.00 mg

So,

k = 0.287 log (2.00/a-x) (a-x is the final amount of the reactants)

⇒ 0.238 = 0.287 log(2.00/a-x)

⇒ (0.238/0.287) = log(2.00/a-x)

⇒ 0.829 = log(2.00/a-x)

⇒ (2.00/a-x) = [tex]10^{0.829}[/tex] = 6.745

⇒ (a-x) = 2.00/6.745 = 0.296 mg

Therefore, the remaining polonium is 0.296 mg after 8.00 years.

learn more about first order kinetics here:

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