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If 317. 7 coulombs was used in an electrolytic cell, how many grams of zn would we expect to be plated from a zn2 solution onto an electrode?

Sagot :

The amount of Zn plated from a [tex]Zn^{2+}[/tex]  solution is [tex]1.07[/tex]×[tex]10^{-1}[/tex] grams.

In this question, it is given that of 317.7 coulombs was used in an electrolytic cell, i.e,

The amount of charge = 317.7 coulombs

The amount of charge of 1 mole of electrons = 96485.3 coulombs   (FARADAY’S CONSTANT)

Now,    the number of electrons = amount of charge given / charge of 1 mole of electrons

            The number of electrons =  [tex]\frac{317.7}{96485.3}[/tex]  =  [tex]3.29[/tex]×[tex]10^{-3}[/tex]

 

According to reaction occurring, 2 moles of electrons are required to convert 1 mole of   to Zn which is plated on the electron, so the moles of Zn plated will be half the moles of electrons, i.e.,

                                                          [tex]\frac{3.29}{2}[/tex]×[tex]10^{-3}[/tex]  =  1.645×[tex]10^{-3}[/tex]

Now, we know that the molar mass of zinc is 65.38gm/mole,

          Number of moles = mass in grams / molar mass

          Mass in grams = number of moles × molar mass

          Mass in grams =  ([tex]1.645[/tex]×[tex]10^{-3}[/tex]) × 65.38  =  0.1075 gm.

CONCLUSION: It concludes that the amount of Zn plated from a   solution is [tex]1.07[/tex]×[tex]10^{-1}[/tex] gm.

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