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How many different products can be formed from a poorly planned crossed aldol addition?
a. 1
b. 2
c. 3
d. 4
e. 5


Sagot :

There are 4 different products will be formed from a poorly planned crossed aldol addition.

In a crossed aldol condensation, two distinct ketone and aldehyde reactants are used. Due to the possibility of several enolate nucleophiles as well as multiple carbonyl electrophiles, similar reactions typically result in a variety of distinct condensation products.

Ethanol and propanol undergo cross-aldol condensation, which results in two products:

  • one where ethanol serves as an enolate ion and the other where propanol serves as an enolate ion.
  • 2-Methylbut-2-enal and Pent-2-enal are just the two cross-aldol derivatives.

Therefore, the correct answer will be option (d)

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There are four different products can be formed from a poorly planned crossed aldol addition.

So the correct option is D

Two distinct ketone and aldehyde reactants are used in a crossed condensation reaction. Due to presence of distinct ketone and aldehyde reactants there are possibility of formation of several enolate ion nucleophiles as well as multiple carbonyl electrophile .

Example : Ethanal and propanone undergoes cross-aldol condensation reaction and give results in two products.

First case: ethanal acts as enolate ion

Second case: propanone acts as enolate ion

Third case: when self condensation is also a product.

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