What is the carbon nucleophile which attacks molecular bromine in the acid-catalyzed α-bromination of a ketone?

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03-08-2022
Chemistry

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What is the carbon nucleophile which attacks molecular bromine in the acid-catalyzed α-bromination of a ketone?

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smecloudbird18 smecloudbird18 · Answer 1 · 2022-08-09T06:18:00-04:00

The enol carbon or ∝-carbon nucleophile attacks at molecular bromine in the acid-catalyzed α-bromination of a ketone

Treatment of ketones with bromine in the presence of acid will results in formation of a new C-Br bond at the alpha position. The purpose of the acid is to catalysed formation of the enol from ketone , which is active nucleophile in the reaction. This reaction is called haloform reaction which is used to identify the methyl substituted ketone in the presence of aldehyde.

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