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when the rate of vaporization equals the rate of condensation, the system will eventually reach equilibrium at 1000 c. equilibrium occurs when two opposing processes happen at the same rate. condensation occurs when gas changes to liquid, whereas vaporization occurs when liquid changes to gas, so at equilibrium, these two processes occur simultaneously. a given amount of time equals one liquid molecule converted to one gas molecule converted to one liquid molecule converted to one gas molecule.

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Nearly all of us have heated a pan of water with the lid on only to hear the lid rattle and hot water fall onto the burner moments later.

A liquid's molecules enter the gaseous phase when heated because they have enough kinetic energy to overcome the forces holding them in the liquid. By doing this, they produce a population of molecules in the vapor phase above the liquid, which leads to the creation of a pressure—the liquid's vapor pressure. The vapor was able to escape in the scenario we described because there was enough pressure to cause the lid to move. if a sealed vessel is used to hold the vapor.

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