Through an unprecedented coupling of aryl iodides and methyl ketones in the presence of silver triflate, these complexes with distinctive catalytic activity enable the quick synthesis of 1,3-disubstituted naphthalenes.
What is the process of naphthalene synthesis?
A methyl ketone is first arylated on a Pd catalyst, and then it is cyclized with a second equivalent of a ketone to complete the transition. This ketone arylation process is significant since it takes place in oxidizing circumstances, which points to the use of dimeric Pd catalysts with greater oxidation states.
The mechanism involving Pd(III) bimetallic catalysis at a high oxidation state on the basis of measurements and DFT calculations. We confirm the significance of the palladium catalyst for both arylation and cyclization for naphthalene production because these new bimetallic complexes exhibit reactivity that is not seen with monometallic Pd catalysts.
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