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Sagot :
Species with the following molecular electronic configurations are: With 15 electrons, O2+: "1s2" + "*1s2" + "2s2" + "*2s2" + "2pz2" + "2px2" = "2py2" with 13 electrons, N2+: 2px2 = 2py2 + 2pz1 = 1s2, *1s2, 2s2, *2s2, etc.
According to electronic configurations, each electron moves individually within an orbital while being surrounded by an average field produced by all other orbitals. Slater determinants or configuration state functions are used to mathematically describe configurations. For systems with only one electron, each configuration of the electron has a certain amount of energy associated with it, and under certain circumstances, the electron can switch between configurations by emitting or absorbing a quantum of energy in the form of a photon. Understanding the structure of the periodic table of elements requires knowledge of the electron configuration of various atoms.
Oxygen (16 electrons)= 1s2, *1s2, 2s2, *2s2, and 2pz2 2px2 = 2py2, while 2px1 = 2py1
N2, with 14 electrons:
2px2 = 2py2 + 2pz2 = 1s2, *1s2, 2s2, *2s2, etc.
Bond order and length are known to be inversely correlated.
Bond order is equal to 1/2 [number of bonding e - number of anti bonding e].
Bond order for N2+ is 1/2 (9 minus 4) equals 2.5.
Bond order for N2 is equal to 1/2 (10 - 4) = 3.
O2bond +'s order is 1/2 (10-5), which equals 2.5.
The bond order for oxygen is 1/2 (10 - 6) = 2.
N2+ has a longer bond length because its bond order is bigger than that .
Learn more about electronic configurations here
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