MgCl2 has a theoretical van’t Hoff factor of 3 because it dissociates into three ions when dissolved in water. The measured value of the van’t Hoff factor for MgCl2 is typically no higher than 2.7. Explain why measured values of the van’t Hoff factors for ionic compounds are always lower than the theoretical values.

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06-12-2022
Chemistry

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MgCl2 has a theoretical van’t Hoff factor of 3 because it dissociates into three ions when dissolved in water. The measured value of the van’t Hoff factor for MgCl2 is typically no higher than 2.7. Explain why measured values of the van’t Hoff factors for ionic compounds are always lower than the theoretical values.

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