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Sagot :
In both the structures shown, replacement of ha and hb, in turn, with an atom z will produce two different compounds that are diastereomers of each other. ha and hb are therefore diastereomer -topic and will give different or distinct nmr signals.
Stereoisomers that are not enantiomers or related as object and mirror images are known as stereoisomers. Diastereomers are not mirror images of one another and cannot be superimposed, in contrast to enantiomers which are. Diastereomers can differ in their reactivity and physical characteristics. They differ in their melting points, boiling points, and densities. There are at least two stereocenters there.
It is simple to mix up diasteromers with enantiomers. Three-bromo-2-butanol, for instance, has four steroisomers. SS, RR, SR, and RS are the four potential combinations (Figure 1). One of the molecules is both the diasteromer and the enantiomer of each of the other two molecules (SS is enantiomer of RR and diasteromer of RS and SR). SS's mirror.
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