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Octane has the strongest IMFs, while 2,2,4-Trimethylpentane has the weakest IMFs. Since octane has the most surface area, its polarizability is the highest out of the three molecules, and stronger IMFs directly correlate to a higher boiling point. 2,2,4-Trimethylpentane has the lowest surface area, so it is the least polarizable and has the lowest boiling point.

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