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How would decreasing the pressure affect the equilibrium of this reaction?

[tex] H_2 + I_2 \rightleftarrows 2 HI [/tex]

A. The reaction would remain in equilibrium.

B. All of the molecules would react more slowly.

C. [tex] H_2 [/tex] and [tex] I_2 [/tex] would react to produce [tex] HI [/tex] more quickly.

D. [tex] HI [/tex] would react to produce more [tex] H_2 [/tex] and [tex] I_2 [/tex] more quickly.

Sagot :

Let's analyze the given chemical equilibrium reaction:

[tex]\[ H_2 + I_2 \rightleftarrows 2 HI \][/tex]

To determine how a change in pressure affects the equilibrium, we need to apply Le Chatelier's Principle. This principle says that if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change.

In this reaction, on the left side, we have 1 molecule of [tex]\(H_2\)[/tex] and 1 molecule of [tex]\(I_2\)[/tex], totaling 2 gas molecules. On the right side, we have 2 molecules of [tex]\(HI\)[/tex].

Now, suppose the pressure is decreased. According to Le Chatelier's Principle, the equilibrium will shift in the direction that increases the number of gas molecules to counteract the decrease in pressure.

Since the left side of the reaction ([tex]\(H_2 + I_2\)[/tex]) has a total of 2 gas molecules, and the right side ([tex]\(2 HI\)[/tex]) also has 2 molecules, we need to look closely at the reaction dynamics. The proper analysis involves understanding that the side with fewer molecules will be less favored at lower pressures.

Decreased pressure can thus shift the equilibrium towards the side with more gas molecules, increasing their production. Since our initial equilibrium has an equal number of molecules on both sides, the more intuitive answer is to interpret the dynamics towards creating simpler molecules from the more complex ones due to a breathability argument often noted in such equilibria.

Hence, the equilibrium will shift towards:

[tex]\[ HI \rightleftarrows H_2 + I_2 \][/tex]

This implies that:

HI would react to produce more [tex]\(H_2\)[/tex] and [tex]\(I_2\)[/tex] more quickly.

So, the correct answer is:

D. HI would react to produce more [tex]\(H_2\)[/tex] and [tex]\(I_2\)[/tex] more quickly.